@article {58230, title = {Near-Infrared Spectrally Selective Plasmonic Electrochromic Thin Films}, journal = {Advanced Optical Materials}, volume = {1}, year = {2013}, month = {03/2013}, pages = {215 - 220}, abstract = {

A plasmonic electrochromic effect in which electrochemical doping reversibly modulates near-infrared surface plasmon absorption of aluminium-doped zinc oxide and tin-doped indium oxide nanocrystals is reported. Optical performance, switching kinetics, and cycling durability point to high-performance NIR selective plasmonic electrochromic coatings based on earth-abundant materials.

}, keywords = {aluminum zinc oxide, indium tin oxide, nanocrystal, spectroelectrochemistry, surface plasmon}, doi = {10.1002/adom.201200051}, author = {Guillermo Garcia and Raffaella Buonsanti and Anna Llordes and Evan L. Runnerstrom and Amy Bergerud and Delia J. Milliron} } @article {58229, title = {Regional performance targets for transparent near-infrared switching electrochromic window glazings}, journal = {Building and Environment}, volume = {61}, year = {2013}, month = {03/2013}, pages = {160 - 168}, abstract = {

With building heating and cooling accounting for nearly 14\% of the national energy consumption, emerging technologies that improve building envelope performance have significant potential to reduce building energy consumption. Actual savings from these technologies will depend heavily upon their performance in diverse climate and operational conditions. In many cases, early-stage research can benefit from detailed investigation in order to develop performance thresholds and identify target markets. One example, a dynamic, highly transparent, near-infrared switching electrochromic (NEC) window glazing, is the focus of this investigation. Like conventional electrochromics, the NEC glazing can dynamically tune its optical properties with a small applied voltage. Consequently, the glazing can block or transmit solar heat to reduce cooling or heating loads, respectively. Unlike conventional electrochromics, NEC glazings remain transparent to visible light, causing no adverse effect to daylighting or building aesthetics. This study utilizes the software COMFEN to simulate a broad range of NEC performance levels, for commercial and residential buildings in 16 climate-representative reference cities. These simulations are the basis for identifying performance levels necessary to compete with existing static technologies. These results indicate that energy savings are strongly influenced by blocking-state performance. Additionally, residential applications have lower performance requirements due to their characteristic internal heat gains. Finally, the most dynamic NEC performance level is simulated in competition with high performing static alternatives. Here heating and cooling energy savings range from 5 to 11\ kWh/m2 yr for commercial and 8{\textendash}15\ kWh/m2 yr for residential, in many regions on the order of 10\%.

}, keywords = {Dynamic windows, Electrochromic glazings, NIR-switching, Performance targets, Solar heat gain}, issn = {03601323}, doi = {10.1016/j.buildenv.2012.12.004}, author = {Nicholas DeForest and Arman Shehabi and Guillermo Garcia and Jeffery B. Greenblatt and Eric R. Masanet and Eleanor S. Lee and Stephen E. Selkowitz and Delia J. Milliron} } @article {58919, title = {Dynamically Modulating the Surface Plasmon Resonance of Doped Semiconductor Nanocrystals}, journal = {Nano Letters}, volume = {11}, year = {2011}, month = {10/2011}, pages = {4415 - 4420}, abstract = {

Localized surface plasmon absorption features arise at high doping levels in semiconductor nanocrystals, appearing in the near-infrared range. Here we show that the surface plasmons of tin-doped indium oxide nanocrystal films can be dynamically and reversibly tuned by postsynthetic electrochemical modulation of the electron concentration. Without ion intercalation and the associated material degradation, we induce a \> 1200 nm shift in the plasmon wavelength and a factor of nearly three change in the carrier density.

}, keywords = {doping, indium tin oxide, nanocrystal, spectroelectrochemistry, surface plasmon}, issn = {1530-6984}, doi = {10.1021/nl202597n}, author = {Guillermo Garcia and Raffaella Buonsanti and Evan L. Runnerstrom and Rueben J. Mendelsberg and Anna Llordes and Andr{\'e} Anders and Thomas J. Richardson and Delia J. Milliron} }